Эпоксидирование олефинов в присутствии молибденовых катализаторов на основе пористых ароматических каркасов

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Аннотация

Проведена модификация структуры пористого ароматического каркаса PAF-30 комплексообразующими группами на основе дипиридиламина, дипиколиламина и ацетилацетона. Синтезированные таким образом материалы использованы в качестве носителей для молибденовых катализаторов эпоксидирования: PAF-30-dpa-Mo, PAF-30-dpcl-Mo, PAF-30-AA-Mo. Все полученные материалы были охарактеризованы методами ИК-спектроскопии, низкотемпературной адсорбции-десорбции азота, рентгеновской фотоэлектронной спектроскопии, элементного анализа, просвечивающей электронной микроскопии. Активность катализаторов изучена в эпоксидировании циклогексена, гексена-1, октена-1 и стирола. Исследована возможность повторного использования катализаторов на примере эпоксидирования циклогексена.

Об авторах

В. А. Ярчак

Московский государственный университет имени М.В. Ломоносова

Email: yarchakvika@gmail.com
119991, Moscow, Russia

Л. А. Куликов

Московский государственный университет имени М.В. Ломоносова

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

А. Л Максимов

Московский государственный университет имени М.В. Ломоносова;Институт нефтехимического синтеза им. А. В. Топчиева РАН

Email: petrochem@ips.ac.ru
119991, Moscow, Russia; 119991, Moscow, Russia

Э. А Караханов

Московский государственный университет имени М.В. Ломоносова

Автор, ответственный за переписку.
Email: petrochem@ips.ac.ru
119991, Moscow, Russia

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