Mixed Ligand Zinc Complexation with Ornithine and Histidine in Aqueous Solution

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Resumo

The formation of mixed-ligand complexes of various compositions in the Zn–L-histidine (His)–L-ornithine (Orn) system has been studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log K, ΔrG0 ΔrH, ΔrS) of the reactions of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) have been calculated. Based on the comparative analysis of thermodynamic parameters, the most probable method for the coordination of amino acid residues in mixed complexes has been proposed.

Sobre autores

M. Nikitina

Krestov Institute of Solution Chemistry, Russian Academy of Sciences

Email: pyreu@mail.ru
153025, Ivanovo, Russia

M. Gruzdev

Krestov Institute of Solution Chemistry, Russian Academy of Sciences

Email: pyreu@mail.ru
153025, Ivanovo, Russia

D. Pyreu

Ivanovo State University

Autor responsável pela correspondência
Email: pyreu@mail.ru
153025, Ivanovo, Russia

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Declaração de direitos autorais © М.Г. Никитина, М.С. Груздев, Д.Ф. Пырэу, 2023