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UNIVERSAL ELECTROCATALYTIC SYSTEM FOR CONVERSION OF ALCOHOLS INTO CARBONYL COMPOUNDS AND CARBOXY ACID FUNCTIONAL DERIVATIVES

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1. Title Title of document UNIVERSAL ELECTROCATALYTIC SYSTEM FOR CONVERSION OF ALCOHOLS INTO CARBONYL COMPOUNDS AND CARBOXY ACID FUNCTIONAL DERIVATIVES
2. Creator Author's name, affiliation, country V. P. Kashparova; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country E. N. Shubina; Platov South-Russian State Polytechnic University (NPI); Don State Technical University
2. Creator Author's name, affiliation, country D. V. Tokarev; Platov South-Russian State Polytechnic University (NPI)
2. Creator Author's name, affiliation, country G. P. Antropov; Don State Technical University
2. Creator Author's name, affiliation, country I, Yu. Zhukova; Don State Technical University
3. Subject Discipline(s)
3. Subject Keyword(s) electrocatalytic system; pyridine bases; alcohols; carbonyl compounds; esters; anhydrides; nitriles.
4. Description Abstract

A universal catalytic system 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl/KI/pyridine base for the conversion of alcohols into carbonyl compounds and derivatives of carboxylic acids has been developed. The use of pyridine, 2,6-lutidine or collidine made it possible to obtain carbonyl compounds (yield up to 100%) after 2-2.2 F/mol. In the presence of pyridine, aliphatic alcohols are converted to esters (yield up to 35%) after 3-4 F/mol. Acid anhydrides (yield up to 80%) are formed using 2,6-lutidine or collidine after 5-6 F/mol. Nitriles were obtained in the presence of 2,6-lutidine and a source of nitrogen (yield up to 99%) after 3-4 F/mol.

5. Publisher Organizing agency, location The Russian Academy of Sciences
6. Contributor Sponsor(s)
7. Date (DD-MM-YYYY) 01.10.2023
8. Type Status & genre Peer-reviewed Article
8. Type Type Unknown
9. Format File format
10. Identifier Uniform Resource Identifier https://jdigitaldiagnostics.com/0424-8570/article/view/670881
10. Identifier Digital Object Identifier (DOI) 10.31857/S0424857023100079
10. Identifier eLIBRARY Document Number (EDN) YIZUEZ
11. Source Title; vol., no. (year) Èlektrohimiâ; Vol 59, No 10 (2023)
12. Language English=en
13. Relation Supp. Files (31KB)
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14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
15. Rights Copyright and permissions Copyright (c) 2023 В.П. Кашпарова, Е.Н. Шубина, Д.В. Токарев, Г.П. Антропов, И.Ю. Жукова