Gidrooblagorazhivanie lignotsellyuloznoy bionefti (obzor)

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Abstract

В обзоре рассмотрены последние достижения в области переработки лигноцеллюлозной биомассы путем проведения каталитической гидродеоксигенации. Лигноцеллюлозная биомасса - наиболее перспективное растительное сырье для производства жидких моторных топлив или получения индивидуальных мономеров нефтехимического производства. Переработка биомассы может быть реализована несколькими способами, среди которых пиролиз представляется наиболее эффективным. Бионефть, полученная в результате пиролиза биомассы, не может быть использована напрямую в качестве топлива ввиду неудовлетворительных эксплуатационных характеристик, вызванных присутствием кислородсодержащих соединений. Применение селективных катализаторов в процессе гидродеоксигенации позволяет снизить содержание кислорода в бионефти и улучшить ее эксплуатационные свойства. Перспективны бифункциональные каталитические системы, содержащие активные металлические центры и кислотный носитель. Активной фазой катализатора могут выступать благородные (Pt, Pd, Ru) и/или переходные (Ni, Co, Mo) металлы, а также сульфиды и фосфиды переходных металлов. В качестве носителей катализаторов гидродеоксигенации наибольшее применение нашли оксиды металлов (ZrO2, CeO2, Al2O3, TiO2), углерод, цеолиты (ZSM-5, Y, Beta, SAPO-11) и материалы из мезопористого оксида кремния (SBA-15, MCM-41) Однако, внедрение и масштабирование процесса гидродеоксигенации бионефти, полученной в результате пиролиза биомассы, ограничено ввиду быстрой дезактивации катализатора в присутствии воды, спекания активной фазы и выщелачивания кислотными компонентами бионефти. Ввиду этого, разработка катализаторов, характеризующихся высокой активностью и стабильностью в условиях гидродеоксигенации бионефти, - одна из наиболее актуальных задач современной нефтехимии.

About the authors

G. O. Zasypalov

Российский государственный университет нефти и газа (НИУ) имени И.М. Губкина

Email: gleb.zasypalov@mail.ru

V. A. Klimovskiy

Российский государственный университет нефти и газа (НИУ) имени И.М. Губкина

E. S. Abramov

Российский государственный университет нефти и газа (НИУ) имени И.М. Губкина

E. E. Brindukova

Курский государственный аграрный университет им. И.И. Иванова

V. D. Stytsenko

Российский государственный университет нефти и газа (НИУ) имени И.М. Губкина

A. P. Glotov

Российский государственный университет нефти и газа (НИУ) имени И.М. Губкина

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