Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures

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Abstract

The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.02.6]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.02,6.08,10]undecane (TCU-1, a monocyclo­propanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified.

About the authors

A. I. Kazakov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: akazakov@icp.ac.ru
125310, Moscow, Russia

L. S. Yanovskiy

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences; Moscow Aviation Institute (National Research University); Moscow Power Engineering Institute (National Research University)

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia; 125310, Moscow, Russia; 111250, Moscow, Russia

Yu. V. Tomilov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

A. A. Molokanov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences; Moscow Power Engineering Institute (National Research University)

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia; 111250, Moscow, Russia

N. A. Plishkin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia

D. B. Lempert

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia

N. I. Varlamova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia

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