Влияние старения деэмульгатора на его характеристики в синтетических эмульсиях тяжелой нефти
- Авторы: Nunes R.D.1, Silva C.M.1, Rocha P.C.1, Lucas E.F.1,2
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Учреждения:
- Universidade Federal do Rio de Janeiro, Instituto de Macromol�culas
- Universidade Federal do Rio de Janeiro, COPPE
- Выпуск: Том 63, № 4 (2023)
- Страницы: 516-523
- Раздел: Статьи
- URL: https://jdigitaldiagnostics.com/0028-2421/article/view/655598
- DOI: https://doi.org/10.31857/S0028242123040068
- EDN: https://elibrary.ru/OJHBQA
- ID: 655598
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Аннотация
Оценивалось влияние старения деэмульгатора на его характеристики, моделирующее хранение нефти на месторождениях, с использованием синтетической эмульсии вода/нефть, приготовленной из тяжелой нефти и минерализованной пластовой воды при концентрации 55 000 ppm. Были определены характеристики нефти и исследованы некоторые свойства деэмульгатора. Нефть, содержащая 11.6% асфальтенов, идентифицировалась как тяжелая, что способствует стабильности эмульсии вода/нефть. Эффективность деэмульгатора увеличивалась со временем старения, результаты свидетельствовали о том, что происходит простое испарение растворителя-добавки, концентрирующее его активное вещество.
Ключевые слова
Об авторах
Rita De Cassia P. Nunes
Universidade Federal do Rio de Janeiro, Instituto de Macromol�culas
Email: redpessanha@gmail.com
21941598, Rio de Janeiro, Brazil
Carla Michele F. Silva
Universidade Federal do Rio de Janeiro, Instituto de Macromol�culas
Email: petrochem@ips.ac.ru
21941598, Rio de Janeiro, Brazil
Paulo Cristiano S. Rocha
Universidade Federal do Rio de Janeiro, Instituto de Macromol�culas
Email: petrochem@ips.ac.ru
21941598, Rio de Janeiro, Brazil
Elizabete F. Lucas
Universidade Federal do Rio de Janeiro, Instituto de Macromol�culas;Universidade Federal do Rio de Janeiro, COPPE
Автор, ответственный за переписку.
Email: petrochem@ips.ac.ru
21941598, Rio de Janeiro, Brazil; 21941599, Rio de Janeiro, Brazil
Список литературы
- Farah M.A. Petróleo e seus derivados: definição, constituição, aplicação, especificações, caracterização, Rio de Janeiro: LTC, 2012.
- Gauto M. Petróleo e Gás - Princípios de exploração, produção e refino. Porto Alegre: Bookman, 2016.
- Díaz-Prada C.A., Guarin-Arenas F., Gonzalez-Barbosa J.-E., Garcia-Chinchilla C.-A., de Jesus Cotes-Leon E., Rodriguez-Walteros C. // Optimization of electrical submersible pump artificial lift system for extraheavy oils through an analysis of bottom dilution scheme. CTF - Cienc. Tecn. Fut. 2010. V. 4. № 1. P. 63-73. https://doi.org/10.29047/01225383.439
- Boyd J., Parkinson C., Sherman P. Factors affecting emulsion stability, and the HLB concept // J. Colloid and Interface Sci. 1972. V. 41. № 2. P. 359-370. https://doi.org/10.1016/0021-9797(72)90122-1
- Friberg S.E. Emulsion Stability. In: Emulsions - a fundamental and practical approach, sjöblom // J. (ed.). NATO ASI Series. V. 363. Dordrecht: Springer. 1992. https://doi.org/10.1007/978-94-011-2460-7_1
- Maia Filho D.C., Ramalh, J.B.V.S., Spinelli L., Lucas E.F. Aging of water-in-crude oil emulsions: effect on water content, droplet size distribution, dynamic viscosity and stability // Colloids Surf. A: Physicochem. Eng. Asp. 2012. V. 396. P. 208-212. https://doi.org/10.1016/j.colsurfa.2011.12.076
- Maia Filho D.C., Ramalho J.B.V.S., Lucas G.M.S., Lucas E.F., Aging of water-in-crude oil emulsions: Effect on rheological parameters // Colloids Surf. A: Physicochem. Eng. Asp. 2012. V. 405. P. 73-78. https://doi.org/10.1016/j.colsurfa.2012.04.041
- Goodarzi F. and Zendehboudi S., A comprehensive review on emulsions and emulsion stability in chemical and energy industries // Can. J. Chem. Eng. 2018. V. 97. № 1. P. 281-309. https://doi.org/10.1002/cjce.23336
- Yudina N.V., Loskutova Y.V., Nebogina N.A., Water-in-oil emulsions in paraffinic and resinous oils // Petrol. Chemistry. 2022. V. 62. № 2. P. 183-190. https://doi.org/10.1134/S0965544122060068
- Gafonova O.V. and Yarranton H.W. The stabilization of water-in-hydrocarbon emulsions by asphaltenes and resins // J. Colloid Interface Sci. 2001. V. 241. № 2. P. 469-478. https://doi.org/10.1006/jcis.2001.7731
- Nebogina N.A., Prozorova I.V., Savinykh Yu.V., Yudina N.V. The influence of natural surfactants on the stabilization of oil-water emulsion // Petrol. Chemistry. 2010. V. 50. № 2. P. 158-163. https://doi.org/10.1134/S0965544110020131
- Petrov S.M., Ibragimova D.A., Abdelsalam Ya.I.I., Kayukova G.P., Influence of rock forming and catalytic additives on transformation of highly viscous heavy oil // Petrol. Chemistry. 2016. V. 56. № 1. P. 21-26. https://doi.org/10.1134/S0965544116010059
- Orrego-Ruí, J.A. and Ruiz F., Finding a relationship between the composition and the emulsifying character of asphaltenes through FTICR-MS. // CTF - Cienc. Tecn. Fut. 2018. V. 8. № 1. P. 45-52. https://doi.org/10.29047/01225383.90
- Gorbacheva S.N. and Ilyin S.O. Structure, rheology and possible application of water-in-oil emulsions stabilized by asphaltenes // Colloids Surf. A: Physicochem. Eng. Asp. 2021. V. 618. P. 126442. https://doi.org/10.1016/j.colsurfa.2021.126442
- Yudina N.V., Nebogina N.A., Prozorova, I.V. Composition of the resin-asphaltene components in the interfacial layers of water-in-oil emulsions // Petrol. Chemistry. 2021. V. 61. № 5. P. 568-575. https://doi.org/10.1134/S0965544121060050
- Glagoleva O.F. and Kapustin V.M., Improving the efficiency of oil treating and refining processes (review) // Petrol. Chemistry. 2020. V. 60. № 11. P. 1207-1215. https://doi.org/10.1134/S0965544120110092
- Ramalho J.B.V.S., Lechuga F.C., Lucas E.F. Effect of the structure of commercial poly(ethylene oxide-β-propylene oxide) demulsifier bases on the demulsification of water-in-crude oil emulsions: Elucidation of the demulsification mechanism // Quim. Nova. 2010. V. 33. № 8. P. 1664-1670. https://doi.org/10.1590/S0100-40422010000800009
- Ferreira B.M.S., Ramalho J.B.V.S., Lucas E.F., Demulsification of W/O emulsions by microwave radiation: Effect of aging, demulsifier addition and selective heating /// Energy Fuels. 2013. V. 27. № 2. P. 615-621. https://doi.org/10.1021/ef301110m
- Pacheco V.F., Ferreira L.S., Lucas E.F., Mansur C.R.E., Destabilization of petroleum emulsions: Evaluation of the influence of the solvent on additives // Energy Fuels. 2015. V. 5. P. 1659-1666. https://doi.org/10.1021/ef101769e
- Hajivand P. and Vaziri A., Optimization of demulsifier formulation for separation of water from crude oil emulsions // Braz. J. Chem. Eng. 2015. V. 32. P. 107-118. https://doi.org/10.1590/0104-6632.20150321s00002755
- Kang W., Yin X., Yang H., Zhao Y., Huang Z., Hou X., Sarsenbekuly B., Zhu, Z., Wang P., Zhang X., Geng J., Aidarova S. Demulsification performance, behavior and mechanism of different demulsifiers on the light crude oil emulsions // Colloids Surf. A: Physicochem. Eng. Asp. 2018. V. 545. P. 197-204. https://doi.org/10.1016/j.colsurfa.2018.02.055
- Saad M.A., Kamil M., Abdurahman N.H., Yunus R.M., Awad O.I. An overview of recent advances in state-of-the-art techniques in the demulsification of crude oil emulsions // Processes. 2019. V. 7. P. 470. https://doi.org/10.3390/pr7070470
- Society for Testing and Materials, ASTM D4377-00 // Standard test method for water in crude oils by potentiometric Karl Fischer Titration. West Conshohocken, 2011.
- Silva J.C., Maravilha T.S.L., Nunes R.C.P., Lucas E.F. Polymers in the production of crude oil: IV. Extraction of asphaltenes fraction using Soxhlet // J. Mater. Educ. 2019. V. 41. № 5-6. P. 149.
- Garreto M.S.E., Gonzalez G., Ramos A.C., Lucas E.F. Looking for a model solvent to disperse asphaltenes // Chem.Chem.Technol. 2010. V. 4. № 4. P. 317-323. https://doi.org/10.23939/chcht04.04.317
- Vieira L.C., Buchuid M.B., Lucas E.F., Effect of pressure on the crystallization of crude oil waxes. II. Evaluation of crude oils and condensate // Energy Fuels. 2010. V. 24. № 4. P. 2213-2220. https://doi.org/10.1021/ef900761t
- Oliveira L.M.S.L., Nunes R.C.P., Ribeiro Y.L.L., Ribeiro D.M., Coutinho D.A., Azevedo J.C.M., Luca E.F. Wax behavior in crude oils by pour point analyses // J. Braz. Chem. Soc. 2018. V. 29. № 10. P. 2158-2168. https://doi.org/10.21577/0103-5053.20180092
- American Society for Testing and Materials, ASTM D97-17b, Standard Test Method for Pour Point of Petroleum Products. West Conshohocken, 2017.
- Oliveira L.M.S.L., Nunes R.C.P., Pessoa L.M.B., Reis L.G., Spinelli L.S., Lucas E.F., Influence of the chemical structure of additives poly(ethylene-co-vinyl acetate)-based on the pour point of crude oils // J. Appl. Polym. Sci. 2020. V. 137. P. 48969. https://doi.org/10.1002/app.48969
- American Society for Testing and Materials, ASTM D4052, Standard Test Method for Density, Relative Density, API Gravity of Liquids by Digital Density Meter. West Conshohocken, 2018.
- American Society for Testing and Materials, ASTM D664-18e2, Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration. West Conshohocken, 2018.
- Silva J.C. et al. Tratamento de óleo - desemulsificação. Eds. E.F. Lucas, L.S. Ferreira, B.F. Alves. Procedimentos experimentais de avaliação de aditivos poliméricos para a indústria do petróleo. Editora UFRJ: Rio de Janeiro (on press), 2022.
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