Features of Cl K-edge XANES spectra of metal transition complexes {MCl6}n– (M = Rh, Pd, Re, Os, Ir, Pt)

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Abstract

Cl K-edges of a set of chlorides of 4d- and 5d-transition metals {MCl6}n– (M = Rh, Pd, Re, Os, Ir, Pt) were obtained using the “Cosmos” station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical methods made it possible to determine the magnitude of the spin-orbit interaction (SOC) depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, as well as stretched and compressed complexes.

About the authors

A. D. Fedorenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

I. P. Asanov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

T. I. Asanova

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

D. B. Vasilchenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

A. D. Nikolenko

Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”; Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

P. A. Piminov

Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

K. Yu. Karyukina

Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

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Copyright (c) 2023 А.Д. Федоренко, И.П. Асанов, Т.И. Асанова, Д.Б. Васильченко, А.Д. Николенко, П.А. Пиминов, К.Ю. Карюкина