Luminescence systems in diamond at 489 nm

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

In the photoluminescence spectra of natural type Ia diamond crystals, a zero-phonon line with a position of 488.9 nm (2.53 eV) is observed. The excitation spectrum of the system is mirror to the emission spectrum. The 488.9 nm line has phonon repetitions corresponding to an energy of 0.073 eV. A change in temperature from 77 to 313 K shifts the position of the system by 1.01 nm toward the red region, and the decrease in intensity and broadening of full width at half maximum is non-linear. The characteristics of the electron-phonon interaction and distribution in the bulk of the crystals of a defect with a zero-phonon line of 488.9 nm are like the characteristics of defects of a nitrogen-vacancy nature.

Full Text

Restricted Access

About the authors

S. V. Lepekha

Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: Lepekha@igg.uran.ru
Russian Federation, Yekaterinburg

E. A. Vasilyev

Saint Petersburg Mining University

Email: Lepekha@igg.uran.ru
Russian Federation, Saint Petersburg

A. S. Kobuzov

Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences

Email: Lepekha@igg.uran.ru
Russian Federation, Yekaterinburg

D. A. Zedgenizov

Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences

Email: Lepekha@igg.uran.ru
Russian Federation, Yekaterinburg

References

  1. Zaitsev A.M. Optical properties of diamond. Berlin: Springer, 2001. 502 p.
  2. Dischler B. Handbook of spectral lines in diamond. V. 1. Tables and Interpretations. Berlin: Springer, 2012. 468 p.
  3. Walker J. // Rep. Prog. Phys. 1979. V. 42. P. 1607.
  4. Ильин В.Е., Соболев Е.В., Юрьева О.П. // ФТТ. 1970. Т. 12. № 7. С. 2159.
  5. Плотникова С.П., Клюев Ю.А., Парфианович И.А. // Минералог. журн. 1980. Т. 2. № 4. С. 75.
  6. Степанов Ф.А., Емельянова А.С., Ракевич А.Л. и др. // Изв. РАН. Сер. физ. 2017. Т. 81. № 9. С. 1220; Stepanov F.A., Emelyanova A. S., Rakevich A.L. et al. // Bull. Russ. Acad. Sci. Phys. 2017. V. 81. No. 9. P. 1099.
  7. Бокий Г.Б., Безруков Г.Н., Клюев Ю.А. и др. Природные и синтетические алмазы. М.: Наука, 1986. 220 с.
  8. Kupriyanov I.N., Gusev V.A., Borzdov Yu.M. et al. // Diamond. Relat. Mater. 1999. V. 8. No. 7. P. 1301.
  9. Yelisseyev А., Kanda H. // New Diamond. Front. Carbon Technol. 2007. V. 17. No. 3. P. 127.
  10. Nadolinny V.A., Yelisseyev A.P. // Diamond. Relat. Mater. 1994. V. 3. No. 1. P. 17.
  11. Клюев Ю.А., Дуденков Ю.А., Непша В.И. // Геохимия. 1973. № 7. C. 1029; Klyuev Yu. A., Dudenkov Yu. A., Nepsha V.I. // Geochem. Int. 1973. No. 7. P. 781.
  12. Соболев Е.В., Ильин В.Е., Юрьева О.П. // ФТТ. 1969. Т. 11. № 5. С. 1152.
  13. Васильев Е.А., Клепиков И.В., Антонов А.В. // Записки РМО. 2018. T. 147. № 4. С. 114.
  14. Васильев Е.А., Иванов-Омский В.И., Помазанский Б.С., Богуш И.Н. // Письма в ЖТФ. 2004. Т. 30. № 19. С. 7; Vasil’ev E.A., Ivanov-Omskii V.I., Pomazanskii B.S., Bogush I.N. // Tech. Phys. Lett. 2004. V. 30. No. 10. P. 802.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Emission spectra at 360 and 440 nm excitation (a, d) and excitation at 496, 489 nm registration (b, c) of FL of synthetic diamond crystal with 489 nm line (T = 77 K)

Download (257KB)
Indexing metadata
3. Fig. 2. Emission spectrum at 440 nm excitation (a) and excitation at 520, 489 nm registration (b, c) of the FL of natural diamond crystal with 489 nm line (T = 77 K)

Download (196KB)
Indexing metadata
4. Fig. 3. Emission spectra of the phonon-free 488.9 nm line obtained by changing the temperature from 77 to 313 K (a). Temperature dependences of the 488.9 nm line parameters: peak energy (position) (b), FWHM spectral line width (c), inverse intensity (d). Dots indicate experimental data, the line is the result of approximation

Download (328KB)
Indexing metadata

Copyright (c) 2024 Russian Academy of Sciences