Symmetry analysis of Raman spectra of crystals based on angular dependencies

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Abstract

Suggested a method to reconstruct the Raman scattering tensor by studying the angular dependences of Raman line intensities in tiny unoriented microcrystals. The method was verified on well-known calomel Hg2Cl2 model crystals. The spectral line phase-indicators in the Raman spectra reveal different symmetry types of DUT-8 (Ni) metal-organic framework crystals in the open pores and closed pores phases. A technique can be used to reconstruct the Raman scattering tensor of any unoriented crystalline samples.

About the authors

E. V. Golovkina

Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences

Email: shusy@iph.krasn.ru

Kirensky Institute of Physics

Russian Federation, Krasnoyarsk

S. N. Krylova

Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences

Email: shusy@iph.krasn.ru

Kirensky Institute of Physics

Russian Federation, Krasnoyarsk

A. N. Vtyurin

Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences; Siberian Federal University

Email: shusy@iph.krasn.ru

Kirensky Institute of Physics

Russian Federation, Krasnoyarsk; Krasnoyarsk

A. S. Krylov

Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: shusy@iph.krasn.ru

Kirensky Institute of Physics

Russian Federation, Krasnoyarsk

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