Bimetallic PdCu/C and PdCu/C-N Alloy Catalysts for 5-Hydroxymethylfurfural Hydration

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Abstract

The catalytic properties of monometallic and bimetallic xPd(100–x)Cu particles obtained by pulsed laser ablation (PLA) in ethanol followed by their deposition on a carbon support were studied in cascade reactions of 5-hydroxymethylfurfural reduction. The composition and morphology of the PLA-prepared xPd(100–x)Cu particles were studied by UV–visible spectroscopy and transmission electron microscopy. The supported xPd(100–x)Cu/C and xPd(100–x)Cu/C-N catalysts prepared on their basis were additionally studied by X-ray phase analysis and low-temperature nitrogen adsorption. In this work, the effect of the composition of bimetallic alloy particles and their interaction with N-centers of the modified carbon support on the catalytic properties of the supported PdCu/C and PdCu/C-N catalysts was studied.

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About the authors

K. L. Timofeev

National Research Tomsk State University

Email: vodyankina_o@mail.ru
Russian Federation, Tomsk

D. P. Morilov

National Research Tomsk State University

Email: vodyankina_o@mail.ru
Russian Federation, Tomsk

D. A. Goncharova

National Research Tomsk State University

Email: vodyankina_o@mail.ru
Russian Federation, Tomsk

V. A. Svetlichny

National Research Tomsk State University

Email: vodyankina_o@mail.ru
Russian Federation, Tomsk

O. V. Vodyankina

National Research Tomsk State University

Author for correspondence.
Email: vodyankina_o@mail.ru
Russian Federation, Tomsk

T. S. Kharlamova

National Research Tomsk State University

Email: kharlamova83@gmail.com
Russian Federation, Tomsk

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Supplementary files

Supplementary Files
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2. Scheme 1. Scheme of HMF hydrogenation

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3. Fig. 1. Absorption spectra of metal colloids obtained by ILA: 1 - Cu colloid; 2 - Pd colloid; 3 - mixture of Cu and Pd colloids with mass ratio of metals 1 : 1; 4 - 50Pd50Cu colloid after laser treatment of colloid mixture

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4. Fig. 2. Typical TEM images of colloidal particles obtained by ILA in ethyl alcohol: Cu (a); Pd (b); 50Pd50Cu (c)

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5. Fig. 3. Adsorption-desorption isotherms (a) and pore size distribution (b) for the original and nitrogen-modified carrier

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6. Fig. 4. Typical X-ray diffraction patterns of xPd(100-x)Cu/C deposited samples

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7. Fig. 5. Catalytic performance of xPd(100-x)Cu/C samples. Conditions: 160°C, 15 atm H2, 4 h of reaction

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8. Fig. 6. Catalytic performance of xPd(100-x)Cu/C-N samples obtained when the reaction was carried out for 4 (a) and 1 h (b). Conditions: 160°C, 15 atm H2

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