Конденсация циклогексанона с 2-метилфураном в присутствии модифицированных сульфогруппами пористых ароматических каркасов

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Abstract

Модифицированные сульфогруппами пористые ароматические каркасы исследованы в качестве катализаторов конденсации циклогексанона с 2-метилфураном. Количественный выход целевого продукта — 1,1-бис(5-метил-2-фурил)циклогексана — достигается при температуре 60°С, соотношении 2-метилфуран: циклогексанол = 2 за 4 ч. Катализатор может быть использован многократно без дополнительной регенерации.

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About the authors

Шан Лян

Московский государственный университет имени М. В. Ломоносова

Email: mailforleonid@mail.ru
ORCID iD: 0009-0004-2410-1727

химический факультет

Russian Federation, 119991, Москва

Леонид Андреевич Куликов

Московский государственный университет имени М. В. Ломоносова

Author for correspondence.
Email: mailforleonid@mail.ru
ORCID iD: 0000-0002-7665-5404

химический факультет

Russian Federation, 119991, Москва

Юлия Сергеевна Кардашева

Московский государственный университет имени М. В. Ломоносова

Email: mailforleonid@mail.ru
ORCID iD: 0000-0002-6580-1082

химический факультет

Russian Federation, 119991, Москва

Мария Владимировна Теренина

Московский государственный университет имени М. В. Ломоносова

Email: mailforleonid@mail.ru
ORCID iD: 0000-0002-4336-9786

химический факультет

Russian Federation, 119991, Москва

Наталья Александровна Синикова

Московский государственный университет имени М. В. Ломоносова

Email: mailforleonid@mail.ru
ORCID iD: 0000-0001-7196-0082

химический факультет

Russian Federation, 119991, Москва

Эдуард Аветисович Караханов

Московский государственный университет имени М. В. Ломоносова

Email: mailforleonid@mail.ru
ORCID iD: 0000-0003-4727-954X

химический факультет

Russian Federation, 119991, Москва

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Supplementary files

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2. Scheme 1. Scheme of catalyst synthesis.

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3. Scheme 2. Scheme of the condensation reaction of 2-methylfuran and cyclohexanone.

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4. Fig. 1. IR spectra of the synthesized materials.

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5. Fig. 2. Condensation of cyclohexanone with 2-methylfuran at different ratios of reactants. Conditions: 20 mg PAF-30-SO3H, 0.4 mL cyclohexanone, 0-0.7 mL 2-methylfuran, 60°C, 1 h, 1 MPa N2. Product yields were calculated based on the conversion of cyclohexanone.

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6. Fig. 3. Dependence of the yield of the condensation products of cyclohexanone and 2-methylfuran on the amount of catalyst (a) and process temperature (b). Conditions: 1) 0.4 mL cyclohexanone, 0.7 mL 2-methylfuran, 60°C, 1 h, 1 MPa N2; 2) 5 mg PAF-30-SO3H, 0.4 mL cyclohexanone, 0.7 mL 2-methylfuran, 1 h, 1 MPa N2.

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7. Fig. 4. Accumulation plot of condensation products of 2-methylfuran and cyclohexanone. Conditions: 5 mg PAF-30-SO3H, 0.4 mL cyclohexanone, 0.7 mL 2-methylfuran, 60°C, 1 MPa N2.

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8. Fig. 5. Reuse of PAF-30-SO3H catalyst (5%) in the condensation of 2-methylfuran and cyclohexanone. Reaction conditions: 5 mg PAF-30-SO3H, 0.4 mL cyclohexanone, 0.7 mL 2-methylfuran, 60°C, 1 h, 1 MPa N2.

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