Deactivation of triplet states of the metalloporphyrins by molecular oxygen

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The values of the phosphorescence decay time of the metalloporphyrins upon selective excitation into the absorption bands and the atmospheric concentration of molecular oxygen in solution has been recorded at 293 K. It was demonstrated that the decay time of triplet states depends on the polarity of the solvents, as well as on the wavelength of the excitation.

Full Text

Restricted Access

About the authors

A. S. Starukhin

B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus

Author for correspondence.
Email: a.starukhin@ifanbel.bas-net.by
Belarus, Minsk

A. Yu. Ilyin

B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus

Email: a.starukhin@ifanbel.bas-net.by
Belarus, Minsk

T. A. Pavich

B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus

Email: a.starukhin@ifanbel.bas-net.by
Belarus, Minsk

References

  1. Gu J., Peng Y., Zhou T. et al. // Nano Res. Energy. 2022. V. 1. Art. No e9120009.
  2. Park J., Lee J., Jang W. // Coord. Chem. Rev. 2020. V. 407. No. 4. Р. 213157.
  3. Park J., Hong K., Lee H. et al. // Acc. Chem. Res. 2021. V. 54. No. 9. Р. 2249.
  4. Shi Y., Zhang F., Linhardt R. // Dyes Pigments. 2021. V. 188. Art. No. 109136.
  5. Старухин А.С., Павич Т.А., Романенко А.А. и др. // Изв. РАН. Сер. физ. 2022. Т. 86. № 6. С. 781; Starukhin A.S., Pavich T.A., Ramanenka A.A. et. al // Bull. Russ. Acad. Sci. Phys. 2022. V. 86. No. 6. Р. 655.
  6. Marian C. // Advanced Review. 2012. V. 2. No. 2. Р. 187.
  7. Darwent J., Douglas P., Harriman A. et al. // Coord. Chem. Rev. 1982. V. 4. No. 6. P. 83.
  8. Uhl R., Meyer B., Desel H. // J. Biochem. Biophys. Meth. 1984. V. 10. No. 1—2. P. 35.
  9. Джагаров Б.М., Салохиддинов К.И. // Опт. и спектроск. 1981. Т. 51. № 5. С. 841.
  10. Джагаров Б.М., Гуринович Г.П., Новиченков В.Е. и др. // Xим. физика. 1987. T. 6. № 5. С. 1069.
  11. Старухин А.С., Панарин А.Ю. // Журн. прикл. спектроск. 2023. Т. 90. № 5. С. 747; Starukhin A.S., Panarin A.Yu. // J. Appl. Spectrosc. 2023. V. 90. Nо. 5. Р. 1037.
  12. Sakamoto K., Ohno-Okumura E. // Materials. 2009. V. 2. Nо. 3. Р. 1127.
  13. Sessler J., Mozaffari А., Johnson A. // Organic Syntheses. 2003. V. 70. Р. 68.
  14. Старухин А.С., Романенко А.А., Плавский В.Ю. // Опт. и спектроск. 2022. Т. 130. № 5. С. 709; Statrukhin A.S., Romanenko A.A., Plavskii V.Yu. // Opt. Spectrosc. 2022. V. 130. No. 5. P. 319.
  15. Старухин А.С., Павич Т.А., Романенко А.А. и др. // Изв. РАН. Сер. физ. 2022. Т. 86. № 6. С. 781; Starukhin A.S., Korol Yu.D., Pavich A.A. et al. // Bull. Russ. Acad. Sci. Phys. 2022. V. 86. No. 6. Р. 650.
  16. Smith G.J. // J. Chem. Soc. Fаraday Trans. 1982. V. 78. No. 2. Р. 769.
  17. Zhan X., Lee W., Sudhakar L.K. et al. // Inorg. Chem. 2021. V. 60. No. 6. P. 8442.
  18. Darmanyan A.P. // Chem. Phys. Lett. 1983. V. 96. No. 3. P. 383.
  19. Montalti M., Credi A., Prodi L., Gandolfi M. // In: Handbook of photochemistry. Materials science. Boca Raton: SRC, Taylor & Francis Group, 2006. P. 542.
  20. Harriman A. // J. Chem. Soc. Faraday Trans. 1981. V. 77. No. 7. P. 1281.
  21. Ганжа В.А., Гуринович Г.П., Джагаров Б.М. и др. // Журн. прикл. спектроск. 1989. Т. 50. № 4. С. 618; Ganzha V.A., Gurinovich G.P., Dzhagarov B.M. et al. // J. Appl. Spectrosc. 1989. V. 50. Nо. 4. Р. 402.

Supplementary files

Supplementary Files
Action
1. JATS XML
2. Fig. 1. Structural formulae of 2,3,7,8,12,13,17,18-octaethylporphyrin (a) and 5,10,15,20-tetraphenylporphyrin (b), where M = Pd- and Pt-

Download (139KB)
3. Fig. 2. Absorption spectra for Pt-OER in TOL at different optical densities of solutions (a) and phosphorescence spectrum of Pt-OER in TOL (λvozb = 382 nm) (b) at atmospheric oxygen concentration and 293 K

Download (119KB)
4. Fig. 3. Absorption spectra of Pd-TPR (a) in DCM at different optical densities of the solutions, and fluorescence and phosphorescence spectra (b) of Pd-OER in TOL (1) and Pd-TPR in DCM (2) at atmospheric oxygen concentration and 293 K

Download (136KB)

Copyright (c) 2024 Russian Academy of Sciences