Influence of metallophilic interactions on physicochemical properties of ion-conducting glass systems (1-x)(0.27Sb2Se3–0.73GeSe2)-xAg2Se

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Abstract

The influence of silver selenide concentration on plasticity, microfate and softening temperature interrelationship, energy of metal atoms in chalcogenide system (1-x)(0.27Sb2Se3–0.73GeSe2)-xAg2Se was presented. Particular attention is paid to a multiple increase in plasticity with an increase in silver selenide content in chalcogenide glasses. The observed effects are associated with the formation of metallophilic interactions of silver-silver. The studies are supplemented by the results of impedancemetry, due to the fact that metallophilic interactions in chalcogenide glass can actively influence not only the glass transition temperature, but also many other important properties, including the mechanism of electronic and ion conductivity.

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About the authors

V. V. Tomaev

St. Petersburg Institute of Technology (Technical University); Saint Petersburg State University

Author for correspondence.
Email: tvaza@mail.ru
Russian Federation, Saint Petersburg; Saint Petersburg

Y. S. Tverjanovich

Saint Petersburg State University

Email: tys@bk.ru
Russian Federation, Saint Petersburg

S. S. Lunkov

Saint Petersburg State University

Email: tvaza@mail.ru
Russian Federation, Saint Petersburg

S. А. Zaitseva

St. Petersburg Institute of Technology (Technical University); Saint Petersburg State University

Email: tvaza@mail.ru
Russian Federation, Saint Petersburg; Saint Petersburg

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2 Based on the materials of the lecture at the 17th International Meeting “Fundamental and Applied Problems of Solid State Ionics”, Chernogolovka, June 16–23, 2024.


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